Difference between being paroled into public interest and being paroled to pursue adjustment

You can access the complete instructions for Form I-765 at www.uscis.gov.

What can be done in this case?

Your friend will have to seek a special travel document with the US Embassy abroad.

Do I need a Valid Visa to re-enter into US on my way back from Peurto Rico?

Puerto Rico is considered part of the territorial US. You could confirm documentary requirements with the airline before purchasing travel tickets.

I was confused so am clarifying the answer if anybody can guide and advise greatly appreciated

The Ombudsman's office is NOT the adjudicator's office, assuming that is your question.

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Can I visit US for attending my business related meetings with US customers ? Read details

You would have to apply for a B-1 visa for that purpose, which would not permit employment in the US.

Applying for OPT or GC and what status does the applicant have during the process?

It is hard to clarify, since you do not indicate what your spouse's immigration status is or explain why you haven't already applied for OPT.

based on what you are saying, it sounds like the answer should be "no," however an attorney most likely would not be able to render you such...

If my I-94 expires before we apply for the greencard, will this put my application in bad standing?How long are we able to wait?

Under these circumstances, you would not be ineligible to adjust status solely because your I-94 has expired.

He has no police record , he is clean on everything

Yes, this is possible. You need to discuss whether he is eligible to adjust status or must seek an immigrant visa from outside the US with an...

HS Diploma; assuming you graduated.