I agree with the other statements, you should likley hire counsel to open a probate proceeding which will give you the authroity to gather the assets of the estate and use the court's authority where your brother will not work with you. Unfortunatally this sort of situation is too common.
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Under most States laws a Will is not valid unless signed by the maker while compentent, and done so in front of two wittnesses who have also signed indicating that the maker signed the Will. As such the new Will is likely not valid. While the new Will would not revoke the prior Will, there is a chance that the acts of the maker of the Will revoked the prior Will, such as the maker's destruction of the prior Will or other evidence of its revocation. However, with that said, under most state's...
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I agree with prior responses, this does not sound like a creditors claim, as it arose after the death of the decedent. As such you should be paid as a priority claim with other administrative costs. If the personal representative refuses, you can file an action to collect the debt obligation. However, you should have it reviewed by an attorney should the PR continue to refuse payment.
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