You have not provided nearly enough details to answer your question. Smoking is NOT an accommodation in the same sense as eating or using the restroom. Generally, I do not believe any injury incurred on such an excursion would be compensible.
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That will depend, and your facts are a little light. My recommendation would be to wear natural fibers, and carry a bottle of water in case you ACCIDENTALLY drop your lit cigarette into your smoking buddy's hair.
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I don't believe you would be covered, since your injury would have not arisen out of the course of your employment.
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