More information is required to answer your question. It might be possible for him to adjust his status without leaving the US, but you should schedule a consultation with with an immigration attorney and show the original documents, including your husband's passport, visa and I-94. You should act fast!
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Only very general answers can be given through Avvo. As you state, you case is complicated. You need to retain an experienced immigration attorney to review all the facts and determine what can be done
J Charles Ferrari Eng & Nishimura 213.622.2255 The statement above is general in nature and does not constitute legal advice, as not all the facts are known. You should retain an attorney to review all the facts specific to your case in order to receive advise specific to your case. The statement above does not create an attorney/client relationship. Answers on Avvo can only be general ones, as specific answers would require knowledge of all the facts. As such, they may or may not apply to the question.
The case you are presenting is much too fact specific and complex to be meaningfully answered in a general forum such as Avvo. You need to consult with a competent immigration lawyer in your area for this.
Behar Intl. Counsel 619.234.5962 Kindly be advised that the answer above is only general in nature cannot be construed as legal advice, given that not enough facts are known. It is your responsibility to retain a lawyer to analyze the facts specific to your particular situation in order to give you specific advice. Specific answers will require cognizance of all pertinent facts about your case. Any answers offered on Avvo are of a general nature only, and are not meant to create an attorney-client relationship.