The probability for an Armenian from Yeravan to obtain a U.S. visitor's visa when applying to the U.S. consulate there are, unfortunately, much less than mine in winning the California lottery on a "quick pick". Especially so if the Armenian in question is also the husband of an LPR living in the US...
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He should go to the U.S. Consulate closest to his place fo residece to apply for a tourist visa. The most important issue for him to prove is a compelling reason (such as a business) to return after his brief visit here.
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The facts you present make it highly unlikely that he would get a visitor visa. Your facts also raise questions as to his status, and you should discuss his future immigration status with an attorney.
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