Emergency medical care is almost always covered under the medical provisions of workers' compensation. I would submit the bill to his insurance carrier for payment, if they refuse to bay it, seek a qualified attorney to assist you.
You will not have to pay but it will go much more smoothly if you hire counsel.
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No. Most states will forbid the hospital / Urgent Care from collecting from you if they are aware that the injury is work-related. The Employer may balk, but the WC Insurance will pay or reduce the bill when they become aware of it.
I represent Employers, but I can recommend Worker Attorneys in So Cal if you ask.
Call the Dallas DWC at 214-350-9299 and tell them that you want to report this injury. Under the Labor Code which is the law applied by workers' comp injuries, emergency visits are covered by the employer's workers' comp policy. You can also try calling a local workers' comp lawyer by the name of Matthew Lewis at 972-644-1111 for assistance. Good luck.