All Legal Permanent Residents may request a Social Security Number. Just go down to your local office to apply. To check what documentation you will need you should check the SSA's website.
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IF she has a green card she can work, engage in business and self-employment at will.
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Anyone who has a permanent resident card can, and should, apply for a Social Security Number, whether or not the person intends to work. Go to the nearest Social Security Office and apply.
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If your dependent now has a green card, then s/he can apply for a social security card regardless of whether s/he is working. A social security number is also needed for many other things.
Andrew M. Bramante, Rosner Partners, 216-771-5588. Free telephone consultation. You should always consult with an experienced immigration attorney to make certain that the advice you received is appropriate for your particular immigration case.